Nickel mediated Palladium free photocatalytic Suzuki-coupling reaction under visible light irradiation
The Suzuki coupling is an important, extensively investigated, and manifold approach for C–C bond construction in synthetic chemistry. However, to date, the reaction has been extensively investigated under thermal conditions using palladium-based catalysts. The development of solar light assisted noble-metal free Suzuki coupling represents a green and sustainable approach for such types of reactions. Herein, we describe an efficient, facile, and cost-effective photocatalytic approach for C–C bond formation between aryl halides and phenylboronic acid via Suzuki-cross-coupling using cobalt(II) phthalocyanine complex grafted onto the nickel oxide semiconductor at ambient condition room temperature (RT) and atmospheric pressure. A number of substituted aryl halides have been successfully investigated under the developed protocol and afforded modest to high yields of the various biphenyls. The possible mechanistic pathway suggested the formation of photogenerated aryl radical cation from the phenylboronic acid followed by its coupling with aryl radical anion generated from the electron‐activated aryl halides resulted in the corresponding biaryls. Importantly, the physical mixture of both components, i.e., CoPc and NiO, showed poor efficiency as compared to the developed hybrid photocatalyst. The recovered photocatalyst could readily be recycled for at least six runs without significant decrease in the activity.