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In situ exsolution of Ni particles on the PrBaMn2O5 SOFC electrode material monitored by high temperature neutron powder diffraction under hydrogen

Abstract

NiO has been incorporated into the nominal perovskite composition Pr0.5Ba0.5MnO3-δ to produce, upon heating under hydrogen atmosphere, in situ exsolved Ni-catalyst supported onto the PrBaMn2O5 anode material. Transmission electron microscopy (TEM) and neutron powder diffraction (NPD) showed that initial composition obtained by annealing in air at 950 °C consists of two perovskite phases; orthorhombic Pr0.65Ba0.35Mn0.975Ni0.025O3 (S.G. Ibmm, ~ 75 wt. %) and 2H-hexagonal BaMnO3-δ (S.G. P63/mcm, 25 wt %). On heating the two-phase sample under wet hydrogen, MnO particles exsolve at T ~ 500 °C meanwhile the orthorhombic phase transforms to tetragonal (S.G. I4/mcm) then to cubic (S.G. Pm-3m) at T ~ 665 °C. When the temperature approaches 900 °C, the emergence of Ni metal particles was detected in the neutron diffraction patterns while the two perovskite phases were transforming into a Ni-free layered double perovskite, PrBaMn2O5. In situ real time observation of the structural changes under hydrogen in the 800-900 °C temperature range provided evidence of the simultaneity of Ni exsolution and phase transformation within our timescale resolution. From quantitative Rietveld analysis, the fraction of exsolved nickel represents the whole amount of Ni introduced in the synthesis of the as-prepared PBMN material. Impedance spectroscopy measurements in 5% H2/Ar atmosphere show promising electrochemical performance for the Ni-exsolved layered perovskite electrode with a polarization resistance of 0.4 Ω cm2 at 800 °C (0.135 Ω cm2 at 850 °C) without any optimization.

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Supplementary files

Article information


Submitted
14 Sep 2019
Accepted
21 Dec 2019
First published
23 Dec 2019

J. Mater. Chem. A, 2020, Accepted Manuscript
Article type
Paper

In situ exsolution of Ni particles on the PrBaMn2O5 SOFC electrode material monitored by high temperature neutron powder diffraction under hydrogen

M. Bahout, P. Managutti, V. Dorcet, A. L. G. La Salle, S. Paofai and T. C. Hansen, J. Mater. Chem. A, 2020, Accepted Manuscript , DOI: 10.1039/C9TA10159D

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