Issue 37, 2020

Cellulose nanocrystals for gelation and percolation-induced reinforcement of a photocurable poly(vinyl alcohol) derivative

Abstract

Nanomaterials are regularly added to crosslinkable polymers to enhance mechanical properties; however, important effects related to gelation behavior and crosslinking kinetics are often overlooked. In this study, we combine cellulose nanocrystals (CNCs) with a photoactive poly(vinyl alcohol) derivative, PVA-SbQ, to form photocrosslinked nanocomposite hydrogels. We investigate the rheology of PVA-SbQ with and without CNCs to decipher the role of each component in final property development and identify a critical CNC concentration (1.5 wt%) above which several changes in rheological behavior are observed. Neat PVA-SbQ solutions exhibit Newtonian flow behavior across all concentrations, while CNC dispersions are shear-thinning <6 wt% and gel at high concentrations. Combining semi-dilute entangled PVA-SbQ (6 wt%) with >1.5 wt% CNCs forms a percolated microstructure. In situ photocrosslinking experiments reveal how CNCs affect both the gelation kinetics and storage modulus (G′) of the resulting hydrogels. The modulus crossover time increases after addition of up to 1.5 wt% CNCs, while no modulus crossover is observed >1.5 wt% CNCs. A sharp increase in G′ is observed >1.5 wt% CNCs for fully-crosslinked networks due to favorable PVA-SbQ/CNC interactions. A percolation model is fitted to the G′ data to confirm that mechanical percolation is maintained after photocrosslinking. A ∼120% increase in G′ for 2.5 wt% CNCs (relative to neat PVA-SbQ) confirms that CNCs provide a reinforcing effect through the percolated microstructure formed from PVA-SbQ/CNC interactions. The results are testament to the ability of CNCs to significantly alter the storage moduli of crosslinked polymer gels at low loading fractions through percolation-induced reinforcement.

Graphical abstract: Cellulose nanocrystals for gelation and percolation-induced reinforcement of a photocurable poly(vinyl alcohol) derivative

Supplementary files

Article information

Article type
Paper
Submitted
29 Jul 2020
Accepted
18 Aug 2020
First published
18 Aug 2020

Soft Matter, 2020,16, 8602-8611

Author version available

Cellulose nanocrystals for gelation and percolation-induced reinforcement of a photocurable poly(vinyl alcohol) derivative

R. D. Corder, P. Adhikari, M. C. Burroughs, O. J. Rojas and S. A. Khan, Soft Matter, 2020, 16, 8602 DOI: 10.1039/D0SM01376E

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