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Issue 25, 2020

Fabrication of solvent transfer-induced phase separation bijels with mixtures of hydrophilic and hydrophobic nanoparticles

Author affiliations

Abstract

Bicontinuous interfacially jammed emulsion gels (bijels), in which the oil and water phases are co-continuous throughout the structure, have potential for applications in separation, catalysis, tissue engineering and energy devices. Among the possible fabrication paths, the solvent transfer-induced phase separation (STRIPS) method has proven to be a powerful approach to produce bijels in a continuous fashion with a broad selection of liquids and nanoparticles. The successful formation of bicontinuous domains requires the use of neutrally wetting particles which was achieved by in situ modification of silica nanoparticles with an oppositely charged surfactant. This approach, however, is not ideal for applications that are adversely affected by the presence of surfactant. In this work, we use a pair of nanoparticles, one hydrophilic, and the other hydrophobic, to stabilize STRIPS bijels without any surfactants and show that the ratio of the hydrophilic to hydrophobic nanoparticles required to form stable bijels changes with the polarity of the oil phase. Highly non-polar oils require a smaller ratio than moderately polar oils. Furthermore, if a sufficiently polar oil is selected, STRIPS bijels can be stabilized using only the hydrophilic nanoparticle. Our results demonstrate the potential to imbue the interface of biphasic liquid mixtures such as bijels with multifunctionality by using two functional nanoparticles of opposite polarity.

Graphical abstract: Fabrication of solvent transfer-induced phase separation bijels with mixtures of hydrophilic and hydrophobic nanoparticles

Supplementary files

Article information


Submitted
12 Jan 2020
Accepted
03 Mar 2020
First published
04 Mar 2020

Soft Matter, 2020,16, 5848-5853
Article type
Paper

Fabrication of solvent transfer-induced phase separation bijels with mixtures of hydrophilic and hydrophobic nanoparticles

G. Di Vitantonio, D. Lee and K. J. Stebe, Soft Matter, 2020, 16, 5848 DOI: 10.1039/D0SM00071J

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