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Permselective ion electrosorption of subnanometer pores at high molar strength enables capacitive deionization of saline water

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Abstract

Capacitive deionization with porous carbon electrodes is an energy-efficient water treatment technique limited to the remediation of only brackish water due to the severe efficiency drop at high molar strength. Combining experiment and simulation, our work demonstrates the ability of subnanometer pores for permselective ion electrosorption, which enables capacitive deionization for saline media with high concentrations. Molecular dynamics simulations reveal the origin of permselective ion electrosorption in subnanometer pores at high molar strength. Within the subnanometer range, carbon pores with smaller size become more ionophobic and then express a higher ability of permselective ion electrosorption. This can be understood by the effects of the pore size on the microstructure of in-pore water and ions and the nanoconfinement effects on the ion hydration. These findings provide a new avenue for capacitive deionization of saline water (seawater-like ionic strength) to enable the application of highly concentrated saline media by direct use of porous carbons.

Graphical abstract: Permselective ion electrosorption of subnanometer pores at high molar strength enables capacitive deionization of saline water

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Article information


Submitted
24 Oct 2019
Accepted
14 Dec 2019
First published
16 Dec 2019

Sustainable Energy Fuels, 2020, Advance Article
Article type
Paper

Permselective ion electrosorption of subnanometer pores at high molar strength enables capacitive deionization of saline water

S. Bi, Y. Zhang, L. Cervini, T. Mo, J. M. Griffin, V. Presser and G. Feng, Sustainable Energy Fuels, 2020, Advance Article , DOI: 10.1039/C9SE00996E

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