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Room-temperature synthesis of Ni1−xFex (oxy)hydroxides: structure–activity relationship for the oxygen evolution reaction

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Abstract

Ni–Fe (oxy)hydroxides outperform most of the non-precious metal-based catalysts towards the oxygen evolution reaction (OER). Yet, the phase structure–catalytic activity correlation remains elusive because of the difficulty in synthesizing phase-pure Ni1−xFex (oxy)hydroxides. Here, a simple room-temperature aqueous solution method has been developed to achieve phase-pure Ni1−xFex (oxy)hydroxides with Fe content ranging from 0 to 100 at%. The Ni1−xFex (oxy)hydroxides are simply derived from the metal–hydrazine complex by in situ transformation in alkaline solutions. The structural evolution and catalytic activity of the Ni1−xFex (oxy)hydroxides are comprehensively studied to reveal the relationship between the structure and catalytic activity. The Ni1−xFex (oxy)hydroxides present high activity at x = 0.3–0.7, and only a small overpotential of <260 mV is needed to achieve an anodic current density of 10 mA cm−2 in 1.0 M KOH. In addition, the catalysts exhibit high long-term working stability. It is found that their phase structure and electronic structure are related to the intrinsic activity and that the Fe/Ni ratio affects the electrical conductivity of Ni1−xFex (oxy)hydroxides for optimized performance.

Graphical abstract: Room-temperature synthesis of Ni1−xFex (oxy)hydroxides: structure–activity relationship for the oxygen evolution reaction

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Article information


Submitted
22 Aug 2019
Accepted
03 Dec 2019
First published
05 Dec 2019

Sustainable Energy Fuels, 2020, Advance Article
Article type
Paper

Room-temperature synthesis of Ni1−xFex (oxy)hydroxides: structure–activity relationship for the oxygen evolution reaction

X. Yan, Q. Hu, W. Zhang, T. Li, H. Zhu and Z. Gu, Sustainable Energy Fuels, 2020, Advance Article , DOI: 10.1039/C9SE00701F

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