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Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature

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Abstract

Palladium-catalyzed regioselective di- or mono-arylation of o-carboranes was achieved using weakly coordinating amides at room temperature. Therefore, a series of B(3,4)-diarylated and B(3)-monoarylated o-carboranes anchored with valuable functional groups were accessed for the first time. This strategy provided an efficient approach for the selective activation of B(3,4)–H bonds for regioselective functionalizations of o-carboranes.

Graphical abstract: Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature

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Article information


Submitted
12 Mar 2020
Accepted
03 May 2020
First published
05 May 2020

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2020, Advance Article
Article type
Edge Article

Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature

Y. Liang, L. Yang, B. B. Jei, R. Kuniyil and L. Ackermann, Chem. Sci., 2020, Advance Article , DOI: 10.1039/D0SC01515F

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