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A Germaaluminocene

Abstract

The reactions of dipotassium germa-cyclopenta¬dienediide with two Group 13 dichlorides, Cp*BCl2 and Cp*AlCl2, yield two structurally different products. In the case of boron a borole complex of germanium(II) is obtained. The aluminium halide gave an unprecedented neutral germaaluminocene. Both compounds were fully characterised by multinuclear NMR spectroscopy supported by DFT computations. The molecular structure of the germaaluminocene was determined by XRD.

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Article information


Submitted
21 Jan 2020
Accepted
07 Feb 2020
First published
10 Feb 2020

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2020, Accepted Manuscript
Article type
Edge Article

A Germaaluminocene

T. Müller, L. Albers, M. Schmidtmann and P. Tholen, Chem. Sci., 2020, Accepted Manuscript , DOI: 10.1039/D0SC00401D

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