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Rational design of a high-efficiency, multivariate metal–organic framework phosphor for white LED bulbs

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Abstract

Developing rare-earth element (REE) free yellow phosphors that can be excited by 455 nm blue light will help to decrease the environmental impact of manufacturing energy efficient white light-emitting diodes (WLEDs), decrease their cost of production, and accelerate their adoption across the globe. Luminescent metal–organic frameworks (LMOFs) demonstrate strong potential for use as phosphor materials and have been investigated intensively in recent years. However, the majority are not suitable for the current WLED technology due to their lack of blue excitability. Therefore, designing highly efficient blue-excitable, yellow-emitting, REE free LMOFs is much needed. With an internal quantum yield of 76% at 455 nm excitation, LMOF-231 is the most efficient blue-excitable yellow-emitting LMOF phosphor reported to date. Spectroscopic studies suggest that this quantum yield could be further improved by narrowing the material's bandgap. Based on this information and guided by DFT calculations, we apply a ligand substitution strategy to produce a semi-fluorinated analogue of LMOF-231, LMOF-305. With an internal quantum yield of 88% (λem = 550 nm) under 455 nm excitation, this LMOF sets a new record for luminescent efficiency in yellow-emitting, blue-excitable, REE free LMOF phosphors. Temperature-dependent and polarized photoluminescence (PL) studies have provided insight on the mechanism of emission and origin of the significant PL enhancement.

Graphical abstract: Rational design of a high-efficiency, multivariate metal–organic framework phosphor for white LED bulbs

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Supplementary files

Article information


Submitted
12 Nov 2019
Accepted
09 Jan 2020
First published
10 Jan 2020

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2020, Advance Article
Article type
Edge Article

Rational design of a high-efficiency, multivariate metal–organic framework phosphor for white LED bulbs

W. P. Lustig, Z. Shen, S. J. Teat, N. Javed, E. Velasco, D. M. O'Carroll and J. Li, Chem. Sci., 2020, Advance Article , DOI: 10.1039/C9SC05721H

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