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Current advances in tin cluster chemistry

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Abstract

This perspective summarizes highlights and most recent advances in tin cluster chemistry, thereby addressing the whole diversity of (mostly) discrete units containing tin atoms. Although being a (semi-)metallic element, tin is in the position to occur both in formally positive or negative oxidation states in these molecules, which causes a broad range of fundamentally different properties of the corresponding compounds. Tin(IV) compounds are not as oxophilic and not as prone to hydrolysis as related Si or Ge compounds, hence allowing for easier handling and potential application. Nevertheless, their reactivity is high due to an overall reduction of bond energies, which makes tin clusters interesting candidates for functional compounds. Beside aspects that point towards bioactivity or even medical applications, materials composed of naked or ligand-protected tin clusters, with or without bridging ligands, show interesting optical, and ion/molecule-trapping properties.

Graphical abstract: Current advances in tin cluster chemistry

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Publication details

The article was received on 30 Aug 2019, accepted on 19 Oct 2019 and first published on 21 Oct 2019


Article type: Perspective
DOI: 10.1039/C9SC04363B
Chem. Sci., 2020, Advance Article
  • Open access: Creative Commons BY-NC license
    All publication charges for this article have been paid for by the Royal Society of Chemistry

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    Current advances in tin cluster chemistry

    B. Peters, N. Lichtenberger, E. Dornsiepen and S. Dehnen, Chem. Sci., 2020, Advance Article , DOI: 10.1039/C9SC04363B

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