Achieving polydispersive HDPE by N,N,N-Co precatalysts appended with N-2,4-bis(di(4-methoxyphenyl)methyl)-6-methylphenyl

Abstract

A family of unsymmetrical 2-(2,4-bis(di(4-methoxyphenyl)methyl)-6-MeC₆H₂N)-6-(1-(arylimino)ethyl)pyridine-cobalt dichloride complexes has been synthesized and characterized by NMR spectroscopy, FT-IR spectroscopy and elemental analysis as well as single crystal X-ray diffraction for Co2 and Co4. Activated with either MAO or MMAO, all the cobalt precatalysts displayed high activities toward ethylene polymerization and produced highly linear polyethylenes with high molecular weights as well as wide polydispersities; for example, the performance using Co1/MAO at 50 °C reached 9.17 × 10⁶ g PE (mol of Co)⁻¹ h⁻¹ with the production polyethylene of molecular weight as high as M_w = 3.14 × 10⁵ g mol⁻¹, T_m = 134.3 °C besides its wide polydispersity of M_w/M_n of 54.6. Besides the terminal vinyl group of the resultant polyethylenes, it is rare for a late-transition metal catalyst to achieve highly linear polyethylenes with not only wide polydispersity but also high molecular weights, being similar to high-density polyethylenes produced using Phillips catalyst.