Synthesis of bismuth nanoparticle-loaded cobalt ferrite for electrochemical detection of heavy metal ions

Abstract

As an efficient modified electrode material for the detection of heavy metal ions, bismuth nanoparticles (BiNPs) were loaded on cobalt ferrite (CoFe₂O₄), a unique magnetic photocatalytic material, to fabricate a highly sensitive sensor. The obtained BiNPs@CoFe₂O₄ nanocomposites showed excellent adsorption and electrical conductivity using a Square Wave Anodic Stripping Voltammetry (SWASV) detection method. Under optimized conditions, the BiNPs@CoFe₂O₄/GCE sensor could simultaneously determine Pb²⁺ and Cd²⁺, with detection limits of 7.3 and 8.2 nM, respectively. In addition, the BiNPs@CoFe₂O₄ exhibited acceptable reproducibility and good stability, which indicated great potential for the detection of heavy metal ions in reality.