Issue 23, 2020

Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water

Abstract

RhCl3 catalyzed the exchange reaction of disulfides and hypodiphosphoric acid tetraalkyl esters in water under homogeneous conditions, which indicated the hypodiphosphoric acid tetraalkyl esters to be novel and efficient phosphorylation reagents in water. The reaction was used in the phosphorylation of unprotected glutathione disulfide.

Graphical abstract: Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water

Supplementary files

Article information

Article type
Paper
Submitted
01 Feb 2020
Accepted
23 Mar 2020
First published
06 Apr 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 13820-13823

Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water

M. Arisawa, K. Fukumoto and M. Yamaguchi, RSC Adv., 2020, 10, 13820 DOI: 10.1039/D0RA02377A

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