Issue 22, 2020

Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality

Abstract

This paper presents the synthesis of a coumarin derivative of resorcin[4]arene (1) using a cascade thermolysis/Michael reaction. The influence of the hydrogen bonding system on the conformational rigidity and cyclochirality of the coumarin derivative of resorcin[4]arene was discussed; these properties depended on the proton-donor–acceptor properties of the solvent. Significant differences, which depended on the environment, in the coumarin derivative of resorcin[4]arene fluorescence were observed and discussed.

Graphical abstract: Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality

Supplementary files

Article information

Article type
Paper
Submitted
13 Jan 2020
Accepted
13 Mar 2020
First published
30 Mar 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 12747-12753

Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality

A. Szafraniec and W. Iwanek, RSC Adv., 2020, 10, 12747 DOI: 10.1039/D0RA00368A

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