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Ni-Catalyzed Stereoselective Difunctionalization of Alkynes

Abstract

Tri- and tetrasubstituted olefins are widely present in biologically active molecules and functional materials. However, the methods for stereoselective construction of such moieties are still very limited and extremely challenging. The transition-metal-catalyzed difunctionalization of alkynes is one of the most straightforward and effective choices. In this review, we summarize the progress of nickel-catalyzed alkyne difunctionalization reaction, with an emphasis on the strategy and control of stereochemistry.

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Article information


Submitted
09 Sep 2020
Accepted
13 Oct 2020
First published
13 Oct 2020

Org. Chem. Front., 2020, Accepted Manuscript
Article type
Review Article

Ni-Catalyzed Stereoselective Difunctionalization of Alkynes

W. Liu and W. Kong, Org. Chem. Front., 2020, Accepted Manuscript , DOI: 10.1039/D0QO01097A

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