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Pyridine hydrochloride-catalyzed thiolation of alkenes: divergent synthesis of allyl and vinyl sulfides

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Abstract

A highly efficient and practical protocol for the synthesis of allylic and vinyl sulfides via pyridinium chloride-catalyzed tandem thiolation–elimination of alkenes is described. This tandem protocol offers easy access to both allylic and 1,1-diarylvinyl sulfides under mild conditions with good to excellent yields and excellent functional group tolerance.

Graphical abstract: Pyridine hydrochloride-catalyzed thiolation of alkenes: divergent synthesis of allyl and vinyl sulfides

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Submitted
30 Aug 2020
Accepted
25 Sep 2020
First published
28 Sep 2020

Org. Chem. Front., 2020, Advance Article
Article type
Research Article

Pyridine hydrochloride-catalyzed thiolation of alkenes: divergent synthesis of allyl and vinyl sulfides

S. Liu, L. Wang, Z. Ma, X. Zeng and B. Xu, Org. Chem. Front., 2020, Advance Article , DOI: 10.1039/D0QO01052A

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