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The Regio and Stereoselective Cleavages of P-S/C-S bonds by Lithium and the Formation of P-Stereogenic Functional Phosphine Derivatives

Abstract

Various menthyl containing phosphinothioates were prepared. Using the compounds, an unusual P-promoted cleavage of C-S bond with lithium-naphthalene was examed. The C-S/P-S cleavages could be controlled by the amount of naphthalene and temperature, and the P-S cleavage was confirmed as P-retained, which was used for the stereo-specific formation of C-P bond.

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Article information


Submitted
02 Aug 2020
Accepted
11 Oct 2020
First published
12 Oct 2020

Org. Chem. Front., 2020, Accepted Manuscript
Article type
Research Article

The Regio and Stereoselective Cleavages of P-S/C-S bonds by Lithium and the Formation of P-Stereogenic Functional Phosphine Derivatives

C. Zhao, X. Wang, Z. Li, Y. Zhang, B. Yan, H. Zheng and Q. Li, Org. Chem. Front., 2020, Accepted Manuscript , DOI: 10.1039/D0QO00891E

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