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Ligand-controlled copper-catalyzed 1,2 or 1,4-protoborylation of 2-trifluoromethyl-1,3-conjugated enynes

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Abstract

A novel ligand-controlled highly regioselective synthesis of CF3-substituted homopropargylboronates and homoallenylboronates via copper-catalyzed 1,2 or 1,4-protoborylation of 2-trifluoromethyl-1,3-conjugated enynes with B2pin2 was developed.

Graphical abstract: Ligand-controlled copper-catalyzed 1,2 or 1,4-protoborylation of 2-trifluoromethyl-1,3-conjugated enynes

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Article information


Submitted
15 Apr 2020
Accepted
12 May 2020
First published
13 May 2020

Org. Chem. Front., 2020, Advance Article
Article type
Research Article

Ligand-controlled copper-catalyzed 1,2 or 1,4-protoborylation of 2-trifluoromethyl-1,3-conjugated enynes

J. Li, C. Liu, J. He, S. Xu, X. Zhao, Y. Zhu and S. Cao, Org. Chem. Front., 2020, Advance Article , DOI: 10.1039/D0QO00445F

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