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Issue 11, 2020
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Recent developments in palladium-catalyzed C–S bond formation

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Abstract

Transition metal-catalyzed C–S bond formation reactions have attracted considerable attention in the recent years. In this regard, palladium-catalyzed C–S bond formation is typically attractive because it can effectively assemble structurally diverse unsymmetrical aryl sulfides and functionalized sulfones under mild conditions with high regioselectivities. In this review, palladium-catalyzed C–S bond formation reactions are summarized and discussed in detail with the focus on sulfenylation and sulfonylation reactions involving aryl/heteroaryl C–H bonds, alkynes, aryl halides, electron-rich benzoic acid derivatives, arylhydrazines, and organosilicon reagents. Some representative synthetic strategies and their transformation application along with reaction mechanisms are also highlighted.

Graphical abstract: Recent developments in palladium-catalyzed C–S bond formation

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Article information


Submitted
27 Mar 2020
Accepted
18 Apr 2020
First published
22 Apr 2020

Org. Chem. Front., 2020,7, 1395-1417
Article type
Research Article

Recent developments in palladium-catalyzed C–S bond formation

J. Li, S. Yang, W. Wu and H. Jiang, Org. Chem. Front., 2020, 7, 1395
DOI: 10.1039/D0QO00377H

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