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Preparation of a mechanically interlocked polymer from a linear supramolecular polymer

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Abstract

A novel supramolecular polymer based on the pillar[5]arene/alkyl-1,2,3-triazole recognition motif and a suitable light responsive azobenzene stopper has been constructed. We found that the formation of the supramolecular polymer based on trans-1 is highly dependent on the monomer concentration. Moreover, by the irradiation of a high concentration solution of trans-1 at 365 nm, we successfully transformed this linear supramolecular polymer into a mechanically interlocked polymer composed of cis-1 by photoisomerization.

Graphical abstract: Preparation of a mechanically interlocked polymer from a linear supramolecular polymer

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Article information


Submitted
11 Mar 2020
Accepted
23 Apr 2020
First published
24 Apr 2020

Org. Chem. Front., 2020, Advance Article
Article type
Research Article

Preparation of a mechanically interlocked polymer from a linear supramolecular polymer

Z. Zhang, K. Sun, L. Jin, C. Xie and S. Li, Org. Chem. Front., 2020, Advance Article , DOI: 10.1039/D0QO00315H

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