Jump to main content
Jump to site search


Access to branched allylsilanes by nickel-catalyzed regioselective hydrosilylation of allenes

Author affiliations

Abstract

A Ni(acac)2/Xantphos-catalyzed hydrosilylation of allenes has been developed. It is the first reported example of using a readily available nickel catalyst to produce branched allylsilanes in high yields with exceptional regiocontrol. This Earth-abundant base-metal catalyst proved to be suitable for a broad range of allenes, offering a general and efficient route to branched allylsilanes. A Ni(0)-species involved mechanism is proposed.

Graphical abstract: Access to branched allylsilanes by nickel-catalyzed regioselective hydrosilylation of allenes

Back to tab navigation

Supplementary files

Article information


Submitted
02 Feb 2020
Accepted
18 Mar 2020
First published
21 Mar 2020

Org. Chem. Front., 2020, Advance Article
Article type
Research Article

Access to branched allylsilanes by nickel-catalyzed regioselective hydrosilylation of allenes

J. Zeng, J. Chen, L. Chen and Z. Zhan, Org. Chem. Front., 2020, Advance Article , DOI: 10.1039/D0QO00156B

Social activity

Search articles by author

Spotlight

Advertisements