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Issue 2, 2020
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Iron-catalyzed three-component intermolecular trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and benzoic acids

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Abstract

A new iron-catalyzed intermolecular three-component trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and various commercially available benzoic acids is achieved. A variety of ester-containing organofluorine compounds were synthesized smoothly under mild conditions. The reaction exhibits a broad substrate scope of styrenes and benzoic acids with moderate yields.

Graphical abstract: Iron-catalyzed three-component intermolecular trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and benzoic acids

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Article information


Submitted
05 Nov 2019
Accepted
28 Nov 2019
First published
02 Dec 2019

Org. Chem. Front., 2020,7, 318-323
Article type
Research Article

Iron-catalyzed three-component intermolecular trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and benzoic acids

R. Xu and C. Cai, Org. Chem. Front., 2020, 7, 318
DOI: 10.1039/C9QO01342C

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