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Iron-catalyzed three-component intermolecular trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and benzoic acids

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Abstract

A new iron-catalyzed intermolecular three-component trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and various commercially available benzoic acids is achieved. A variety of ester-containing organofluorine compounds were synthesized smoothly under mild conditions. The reaction exhibits a broad substrate scope of styrenes and benzoic acids with moderate yields.

Graphical abstract: Iron-catalyzed three-component intermolecular trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and benzoic acids

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Publication details

The article was received on 05 Nov 2019, accepted on 28 Nov 2019 and first published on 02 Dec 2019


Article type: Research Article
DOI: 10.1039/C9QO01342C
Org. Chem. Front., 2020, Advance Article

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    Iron-catalyzed three-component intermolecular trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and benzoic acids

    R. Xu and C. Cai, Org. Chem. Front., 2020, Advance Article , DOI: 10.1039/C9QO01342C

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