Janus MXene Nanosheets for Macroscopic Assemblies
The versatile surface chemistry of MXene affords a simple way by which the surface of MXene nanosheets can be modified. Here, by selectively grafting polystyrene onto one side of MXene nanosheet, a new amphiphilic surfactant nanomaterial, termed Janus MXene nanosheets (JMNs) or MXene nanosheet surfactants (MNSs), is designed and synthesized. The prepared JMNs can be dispersed in either water or oil, and can spontaneously assemble at the water-oil interface to reduce the interfacial tension, making a promising solid surfactant to stabilize emulsions. Macroscopic assemblies of JMNs can also be easily prepared by interfacial assembly. Using creamed emulsions as templates, a lightweight, isotropic MXene aerogel was produced in a one-step freeze-drying, where the matrix comprises the anchored PS and the pore structure is commensurate with the parent emulsion.