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Issue 12, 2020
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Recent progress in well-defined higher azaacenes (n ≥ 6): synthesis, molecular packing, and applications

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Abstract

In this review, we will focus on the recent progress in the synthetic strategies, photo-electronic properties, molecular packing modes and applications of azaacenes (n ≥ 6) with single-crystal structures. We will summarize the synthetic methods to approach larger azaacenes and elaborate the relationships between their molecular structures (solid stacking) and their photo-electronic properties. Moreover, the device applications of azaacenes as organic semiconductors are also reviewed.

Graphical abstract: Recent progress in well-defined higher azaacenes (n ≥ 6): synthesis, molecular packing, and applications

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Article information


Submitted
24 Oct 2019
Accepted
19 Dec 2019
First published
19 Dec 2019

Mater. Chem. Front., 2020,4, 3419-3432
Article type
Review Article

Recent progress in well-defined higher azaacenes (n ≥ 6): synthesis, molecular packing, and applications

Z. Zhang and Q. Zhang, Mater. Chem. Front., 2020, 4, 3419
DOI: 10.1039/C9QM00656G

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