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Issue 21, 2020
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Silylation of silanols with hydrosilanes via main-group catalysis: the synthesis of unsymmetrical siloxanes and hydrosiloxanes

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Abstract

Apart from some specific synthetic solutions, a dehydrogenative coupling of silanols with hydrosilanes seems to be the most atom-economical and practical method for the formation of unsymmetrical siloxanes. This goal was accomplished by simple main-group catalysis, utilizing commercially available reagents under mild conditions.

Graphical abstract: Silylation of silanols with hydrosilanes via main-group catalysis: the synthesis of unsymmetrical siloxanes and hydrosiloxanes

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Submitted
27 Jul 2020
Accepted
09 Sep 2020
First published
10 Sep 2020

Inorg. Chem. Front., 2020,7, 4190-4196
Article type
Research Article

Silylation of silanols with hydrosilanes via main-group catalysis: the synthesis of unsymmetrical siloxanes and hydrosiloxanes

K. Kuciński, H. Stachowiak and G. Hreczycho, Inorg. Chem. Front., 2020, 7, 4190
DOI: 10.1039/D0QI00904K

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