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Core and double bond functionalisation of cyclopentadithiophene-phosphaalkenes

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Abstract

The heterofulvenoid cyclopentadithiophene-phosphaalkene is a versatile building block for opto-electronic tuning with donor and acceptor moieties. Both the annulated thienyl rings and the phosphaalkene bond can be functionalised using a variety of chemical transformations, e.g. forming C–C, C–E (E[double bond, length as m-dash]Si, Br) bonds, or oxidation and metal coordination, respectively. Solid-state structures, optical and electronic properties are probed theoretically and experimentally, illustrating the opto-electronic tailoring opportunities at this motif.

Graphical abstract: Core and double bond functionalisation of cyclopentadithiophene-phosphaalkenes

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Article information


Submitted
17 Jun 2020
Accepted
07 Sep 2020
First published
08 Sep 2020

This article is Open Access

Inorg. Chem. Front., 2020, Advance Article
Article type
Research Article

Core and double bond functionalisation of cyclopentadithiophene-phosphaalkenes

J. A. L. Wells, M. A. Shameem, A. K. Gupta and A. Orthaber, Inorg. Chem. Front., 2020, Advance Article , DOI: 10.1039/D0QI00714E

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