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Anisotropic proton conduction realized by a layered vanadium selenite single crystal

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Abstract

The study of anisotropic proton conduction (APC) on a layered-structured vanadium selenite single crystal, namely [H3O][(VO2)3(SeO3)2] (1), reveals the proton conductivity (σ) ratio (σ[100]/σ[001] = 188) at 80 °C under 70% relative humidity (RH) and the proton conduction mechanisms of Grotthuss and Vehicle along the [100] and [001] directions, respectively.

Graphical abstract: Anisotropic proton conduction realized by a layered vanadium selenite single crystal

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Submitted
13 Jan 2020
Accepted
05 Mar 2020
First published
10 Mar 2020

Inorg. Chem. Front., 2020, Advance Article
Article type
Research Article

Anisotropic proton conduction realized by a layered vanadium selenite single crystal

H. Sun, S. Sun, B. Hu, L. Gong, Y. Zou, J. Li, M. Feng and X. Huang, Inorg. Chem. Front., 2020, Advance Article , DOI: 10.1039/D0QI00040J

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