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Issue 7, 2020
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High temperature Fe(iii) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes

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Abstract

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H3ATD) was used to synthesize three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal FeIII ions.

Graphical abstract: High temperature Fe(iii) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes

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Article information


Submitted
29 Nov 2019
Accepted
31 Jan 2020
First published
04 Feb 2020

Inorg. Chem. Front., 2020,7, 1526-1531
Article type
Research Article

High temperature Fe(III) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes

Z. Ouyang, X. Mo, M. Yang, L. Zhong, W. Chen, S. Gao and W. Dong, Inorg. Chem. Front., 2020, 7, 1526
DOI: 10.1039/C9QI01560D

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