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Facile preparation of polycarbonates from bio-based eugenol and 2-methoxy-4-vinylphenol

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Abstract

Two α,ω-diene monomers containing a carbonate structure derived from eugenol and 2-methoxy-4-vinylphenol were successfully synthesized in high yields of 94% and 78%, respectively. With these dienes in hand, a series of poly(thioether carbonates) and unsaturated aromatic–aliphatic polycarbonates with moderate molecular weights (Mn) ranging from 17 100 to 24 400 g mol−1 and tunable thermo-properties were prepared via a thiol–ene click reaction and step growth acyclic-diene-metathesis, respectively.

Graphical abstract: Facile preparation of polycarbonates from bio-based eugenol and 2-methoxy-4-vinylphenol

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Supplementary files

Article information


Submitted
21 Feb 2020
Accepted
29 Jun 2020
First published
30 Jun 2020

Polym. Chem., 2020, Advance Article
Article type
Communication

Facile preparation of polycarbonates from bio-based eugenol and 2-methoxy-4-vinylphenol

M. Huang, D. Bai, Q. Chen, C. Zhao, T. Ren, C. Huang, M. North and H. Xie, Polym. Chem., 2020, Advance Article , DOI: 10.1039/D0PY00291G

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