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Issue 13, 2020
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One-pot synthesis of dual supramolecular associative copolymers by using a novel acrylate monomer bearing urethane and pendant pyridine groups

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Abstract

We here realize a highly efficient synthesis, i.e., one-pot synthesis, of dual supramolecular associative copolymers, by using a novel acrylate monomer (coded as 4PyA) bearing urethane and pendant pyridine groups. In the RAFT copolymerization of 4PyA and ethyl acrylate (EA), the radical reactivity ratios of both 4PyA and EA are analyzed to be close to 1. Blending a metal salt leads to coordination with the pyridine group while the urethane group forms a self-complementary hydrogen bond, generating a dual supramolecular network.

Graphical abstract: One-pot synthesis of dual supramolecular associative copolymers by using a novel acrylate monomer bearing urethane and pendant pyridine groups

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Article information


Submitted
02 Dec 2019
Accepted
01 Mar 2020
First published
06 Mar 2020

Polym. Chem., 2020,11, 2318-2324
Article type
Communication

One-pot synthesis of dual supramolecular associative copolymers by using a novel acrylate monomer bearing urethane and pendant pyridine groups

Y. Oba, M. Hayashi and A. Takasu, Polym. Chem., 2020, 11, 2318
DOI: 10.1039/C9PY01824G

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