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Influence of the –CN substitution position on the performance of dicyanodistyrylbenzene-based polymer solar cells

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Abstract

Molecular engineering of polymer donors is imperative to improve the photovoltaic performance of polymer solar cells (PSCs). Here, we report that the substitution position of the –CN group in dicyanodistyrylbenzene (DCB) moiety-based copolymers greatly affected the molecular packing and photovoltaic performance of PSCs. Four novel copolymers based on DCB units as electron donors and 5,6-difluorobenzo[c][1,2,5]thiadiazole (DFBT) or naphtho[1,2-c:5,6-c′]bis[1,2,5]thiadiazole (NT) units as electron acceptors were designed and synthesized to investigate the effects of altering the –CN substitution position. Density functional theory (DFT) calculations showed that the P-o-derivative copolymers, i.e., those with outer substitution positions, possessed a more planar conjugated backbone than the P-i-derivative copolymers, i.e., those with inner substitution positions, which enhanced the absorption coefficient and provided higher charge mobility. Moreover, two-dimensional (2D) grazing incidence wide-angle X-ray scattering (GIWAXS) patterns showed clearly that the P-o-derivative blends exhibited strong face-on π–π stacking. This ordered polymer packing facilitated charge transport in the vertical direction. In contrast, the P-i-derivative blends were prone to edge-on lamellar stacking. Combining each copolymer with a small molecular acceptor (ITIC-4F), an optimum power conversion efficiency (PCE) of 10% was achieved for the P-o-derivative blend devices, whereas the devices based on the P-i-derivative copolymers exhibited a PCE of only 6.67%. Our comparative research indicates that changing the functional group substitution position could affect molecular packing and molecular properties. This approach provides a path toward the molecular design of more materials for high-performance PSCs.

Graphical abstract: Influence of the –CN substitution position on the performance of dicyanodistyrylbenzene-based polymer solar cells

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Supplementary files

Article information


Submitted
25 Nov 2019
Accepted
15 Jan 2020
First published
17 Jan 2020

Polym. Chem., 2020, Advance Article
Article type
Paper

Influence of the –CN substitution position on the performance of dicyanodistyrylbenzene-based polymer solar cells

B. He, Q. Yin, B. Xie, J. Zhang, R. Xie, Z. Hu, X. Peng, F. Huang and Y. Cao, Polym. Chem., 2020, Advance Article , DOI: 10.1039/C9PY01781J

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