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Issue 7, 2020
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Cleavable coumarin-based oxime esters with terminal heterocyclic moieties: photobleachable initiators for deep photocuring under visible LED light irradiation

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Abstract

Development of efficient unimolecular visible light photoinitiators (PIs) with photobleaching capabilities, which is essential for various biomedical applications and photopolymerization of thick materials, remains an emerging challenge. Based on the photochemistry of heteroaromatic compounds, unimolecular visible light oxime ester PIs (2-O, 2-S, 3-O, and 3-S), which contain coumarin derivatives as visible light chromophores, were designed and synthesized. Photophysical and photochemical properties of these PIs have been investigated using UV-Vis spectroscopy, fluorescence spectroscopy and electron spin resonance (ESR). The oxime-esters photolyse rapidly under 450 nm LED light irradiation, especially 2-S, and have good photobleaching capabilities. Also, we have, for the first time, shown that heterocyclic radicals efficiently initiate free radical polymerization of acrylate monomers. Notably, these photobleaching initiators can be used to induce thiol-based click photopolymerization to prepare materials with a thickness of up to 10 mm.

Graphical abstract: Cleavable coumarin-based oxime esters with terminal heterocyclic moieties: photobleachable initiators for deep photocuring under visible LED light irradiation

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Article information


Submitted
08 Nov 2019
Accepted
30 Dec 2019
First published
02 Jan 2020

Polym. Chem., 2020,11, 1356-1363
Article type
Paper

Cleavable coumarin-based oxime esters with terminal heterocyclic moieties: photobleachable initiators for deep photocuring under visible LED light irradiation

W. Qiu, M. Li, Y. Yang, Z. Li and K. Dietliker, Polym. Chem., 2020, 11, 1356
DOI: 10.1039/C9PY01690B

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