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Recoverable and recyclable nickel–cobalt magnetic alloy nanoparticle catalyzed reversible deactivation radical polymerization of methyl methacrylate at 25 °C

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Abstract

Recyclable Ni–Co alloy nanoparticle catalyzed synthesis of well-defined poly(methyl methacrylate) (PMMA, up to 129 500 g mol−1) with low dispersity (Đ = 1.30) via a reversible deactivation radical polymerization technique is reported. The combined advantages of easier catalyst preparation and handling, predictability, simple recovery and reusability up to multiple cycles without a notable decrease in the control over the polymerization make the process an ideal methodology for the synthesis of tailored polymers.

Graphical abstract: Recoverable and recyclable nickel–cobalt magnetic alloy nanoparticle catalyzed reversible deactivation radical polymerization of methyl methacrylate at 25 °C

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Publication details

The article was received on 27 Jun 2019, accepted on 08 Sep 2019 and first published on 09 Sep 2019


Article type: Communication
DOI: 10.1039/C9PY00942F
Polym. Chem., 2020, Advance Article

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    Recoverable and recyclable nickel–cobalt magnetic alloy nanoparticle catalyzed reversible deactivation radical polymerization of methyl methacrylate at 25 °C

    S. A. Mohammad, S. Shingdilwar and S. Banerjee, Polym. Chem., 2020, Advance Article , DOI: 10.1039/C9PY00942F

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