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Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents

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Abstract

The mild generation of nitrogen-centred radicals from N–F reagents has become a convenient synthetic tool. This methodology provides access to the aminative difunctionalisation of alkenes and alkynes and the radical ring-opening of cyclopropanes, among other similar transformations. This review article aims to provide an overview of recent developments of such processes involving radical reactions and N–F reagents using copper-based catalysts.

Graphical abstract: Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents

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Article information


Submitted
23 Aug 2020
Accepted
10 Oct 2020
First published
13 Oct 2020

Org. Biomol. Chem., 2020, Advance Article
Article type
Review Article

Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents

J. M. Muñoz-Molina, T. R. Belderrain and P. J. Pérez, Org. Biomol. Chem., 2020, Advance Article , DOI: 10.1039/D0OB01743D

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