Issue 43, 2020

Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents

Abstract

The mild generation of nitrogen-centred radicals from N–F reagents has become a convenient synthetic tool. This methodology provides access to the aminative difunctionalisation of alkenes and alkynes and the radical ring-opening of cyclopropanes, among other similar transformations. This review article aims to provide an overview of recent developments of such processes involving radical reactions and N–F reagents using copper-based catalysts.

Graphical abstract: Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents

Article information

Article type
Review Article
Submitted
23 Aug 2020
Accepted
10 Oct 2020
First published
13 Oct 2020

Org. Biomol. Chem., 2020,18, 8757-8770

Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents

J. M. Muñoz-Molina, T. R. Belderrain and P. J. Pérez, Org. Biomol. Chem., 2020, 18, 8757 DOI: 10.1039/D0OB01743D

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