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Recent advances in 1,4-functional group migration-mediated radical fluoroalkylation of alkenes and alkynes

Abstract

Recently, the combination of radical fluoroalkylation of alkenyl or alkynyl moieties and 1,4-functional group migration (1,4-FGM) has emerged as powerful strategy for the synthesis of fluorine-containing compounds. In this article, some representative reactions of 1,4-FGM-mediated radical fluoroalkylation of N-(arylsulfonyl)acrylamides, tertiary alcohol-containing alkynes, tertiary alcohol-containing alkenes and Intermolecular 1,4-FGM-type substrates have been discussed based on the types of substrates.

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Article information


Submitted
08 Aug 2020
Accepted
06 Oct 2020
First published
06 Oct 2020

Org. Biomol. Chem., 2020, Accepted Manuscript
Article type
Review Article

Recent advances in 1,4-functional group migration-mediated radical fluoroalkylation of alkenes and alkynes

Y. Chen, Y. Qu, X. Li and C. Wang, Org. Biomol. Chem., 2020, Accepted Manuscript , DOI: 10.1039/D0OB01649G

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