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An amide hydrogen bond templated [1]rotaxane displaying a peptide motif – demonstrating an expedient route to synthetic mimics of lasso peptides

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Abstract

The rapid synthesis of an amide hydrogen bond templated [1]rotaxane is reported – demonstrating a potential pathway to synthetic analogues of lasso peptides. The structures of the [1]rotaxane and its unthreaded isomer have been characterized by NMR spectroscopy and modelled using DFT calculations.

Graphical abstract: An amide hydrogen bond templated [1]rotaxane displaying a peptide motif – demonstrating an expedient route to synthetic mimics of lasso peptides

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Article information


Submitted
09 Jun 2020
Accepted
23 Jun 2020
First published
24 Jun 2020

This article is Open Access

Org. Biomol. Chem., 2020, Advance Article
Article type
Paper

An amide hydrogen bond templated [1]rotaxane displaying a peptide motif – demonstrating an expedient route to synthetic mimics of lasso peptides

M. J. Young, G. R. Akien and N. H. Evans, Org. Biomol. Chem., 2020, Advance Article , DOI: 10.1039/D0OB01190H

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