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Red-shifted backbone N–H photocaging agents

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Abstract

Light is a uniquely powerful tool for spatiotemporal control of molecular structure, necessitating the development of new photocaging approaches. This communication describes the design, synthesis, and reactivity of two new photoreactive boronic acid reagents for backbone N–H modification and subsequent photocleavage.

Graphical abstract: Red-shifted backbone N–H photocaging agents

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Article information


Submitted
04 May 2020
Accepted
30 May 2020
First published
09 Jun 2020

Org. Biomol. Chem., 2020, Advance Article
Article type
Communication

Red-shifted backbone N–H photocaging agents

A. E. Mangubat-Medina, H. O. Trial, R. D. Vargas, M. T. Setegne, T. Bader, M. D. Distefano and Z. T. Ball, Org. Biomol. Chem., 2020, Advance Article , DOI: 10.1039/D0OB00923G

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