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Issue 21, 2020
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FeCl2 catalyzed direct modification of dihydropyrrolo[2,1-a]isoquinolines with phenols

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Abstract

A mild catalytic modification of dihydropyrrolo[2,1-a]isoquinolines with various phenols via the formation of heteroarene cation radicals as key intermediates has been developed. A range of direct cross-coupling products could be obtained in acceptable to excellent yields (up to 98%) in the presence of FeCl2.

Graphical abstract: FeCl2 catalyzed direct modification of dihydropyrrolo[2,1-a]isoquinolines with phenols

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Supplementary files

Article information


Submitted
03 May 2020
Accepted
11 May 2020
First published
11 May 2020

Org. Biomol. Chem., 2020,18, 4085-4089
Article type
Paper

FeCl2 catalyzed direct modification of dihydropyrrolo[2,1-a]isoquinolines with phenols

H. Cui, Org. Biomol. Chem., 2020, 18, 4085
DOI: 10.1039/D0OB00917B

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