Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.



Efficient copper(i)-catalyzed oxidative intermolecular 1,2-estersulfenylation of styrenes with peroxyesters and disulfides

Author affiliations

Abstract

A simple and practical method for the synthesis of thio-substituted esters through copper(I)-catalyzed intermolecular 1,2-estersulfenylation of styrenes with peroxyesters and disulfides was developed. In this transformation, two new C–S bond and C–O bond were constructed simultaneously under a copper catalyst system, and the transformation exhibits a broad substrate scope and good functional group compatibility. In addition, this method can also be applied to arylthiols. It should be noted that peroxyesters not only acted as nucleophilic reagents but also as oxidants.

Graphical abstract: Efficient copper(i)-catalyzed oxidative intermolecular 1,2-estersulfenylation of styrenes with peroxyesters and disulfides

Back to tab navigation

Supplementary files

Article information


Submitted
20 Apr 2020
Accepted
09 Jun 2020
First published
09 Jun 2020

Org. Biomol. Chem., 2020, Advance Article
Article type
Research Article

Efficient copper(I)-catalyzed oxidative intermolecular 1,2-estersulfenylation of styrenes with peroxyesters and disulfides

Y. Luo, R. Su and H. Yang, Org. Biomol. Chem., 2020, Advance Article , DOI: 10.1039/D0OB00823K

Social activity

Search articles by author

Spotlight

Advertisements