Issue 25, 2020

A one-pot protocol for the fluorosulfonation and Suzuki coupling of phenols and bromophenols, streamlined access to biaryls and terphenyls

Abstract

A one-pot protocol for the fluorosulfation and Suzuki coupling of phenols is described. The tandem reaction proceeds efficiently at room temperature, and various biaryls and biaryl fluorosulfates were obtained in good to excellent yields. Furthermore, biaryl fluorosulfates were utilized as versatile building blocks for the preparation of terphenyls.

Graphical abstract: A one-pot protocol for the fluorosulfonation and Suzuki coupling of phenols and bromophenols, streamlined access to biaryls and terphenyls

Supplementary files

Article information

Article type
Paper
Submitted
24 Feb 2020
Accepted
07 Apr 2020
First published
07 Apr 2020

Org. Biomol. Chem., 2020,18, 4748-4753

A one-pot protocol for the fluorosulfonation and Suzuki coupling of phenols and bromophenols, streamlined access to biaryls and terphenyls

X. Li, T. Zhang, R. Hu, H. Zhang, C. Ren and Z. Yuan, Org. Biomol. Chem., 2020, 18, 4748 DOI: 10.1039/D0OB00406E

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