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Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol–ene coupling (TEC)

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Abstract

Radical thiol–ene coupling was exploited for the first time to prepare imino-disaccharides and multivalent iminosugars starting from sugar thiols and iminosugar alkenes or iminosugar thiols and tetra-allylated calixarene, respectively.

Graphical abstract: Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol–ene coupling (TEC)

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Article information


Submitted
30 Jan 2020
Accepted
13 Feb 2020
First published
21 Feb 2020

Org. Biomol. Chem., 2020, Advance Article
Article type
Communication

Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol–ene coupling (TEC)

R. Zelli, P. Dumy and A. Marra, Org. Biomol. Chem., 2020, Advance Article , DOI: 10.1039/D0OB00198H

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