Catalytic enantioselective decarboxylative nucleophilic addition reactions using chiral organocatalysts

Kengo Hyodo; Shuichi Nakamura

doi:10.1039/D0OB00127A

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Catalytic enantioselective decarboxylative nucleophilic addition reactions using chiral organocatalysts

Kengo Hyodo*^a and Shuichi Nakamura

*^b

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* Corresponding authors

^a Department of Chemistry, School of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
E-mail: hyodo@chem.kindai.ac.jp
Tel: +81-6-4307-3047

^b Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
E-mail: snakamur@nitech.ac.jp
Fax: +81-52-735-5245
Tel: +81-52-735-5245

Abstract

Catalytic decarboxylative reactions are attractive as biomimetic and environmentally friendly reaction processes. This review summarizes the recent results of organocatalytic enantioselective decarboxylative reactions of malonic acid half oxy- or thioesters, β-ketoacids, and related compounds from October 2013 to December 2019.

This article is part of the themed collections: Synthetic methodology in OBC and Catalysis & biocatalysis in OBC

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Article information

DOI: https://doi.org/10.1039/D0OB00127A
Article type: Review Article
Submitted: 20 Jan 2020
Accepted: 19 Mar 2020
First published: 20 Mar 2020

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Org. Biomol. Chem., 2020,18, 2781-2792

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Catalytic enantioselective decarboxylative nucleophilic addition reactions using chiral organocatalysts

K. Hyodo and S. Nakamura, Org. Biomol. Chem., 2020, 18, 2781 DOI: 10.1039/D0OB00127A

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Organic & Biomolecular Chemistry

Catalytic enantioselective decarboxylative nucleophilic addition reactions using chiral organocatalysts

Abstract

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Catalytic enantioselective decarboxylative nucleophilic addition reactions using chiral organocatalysts

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