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Visible-light-mediated borylation of aryl and alkyl halides with a palladium complex

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Abstract

Palladium catalyzed visible-light-mediated borylation of inactivated aryl and alkyl halides is reported; the method provided high yields and excellent functional group compatibility. Furthermore, arylsilicates were synthesized selectively using dimethylphenylsilyl boronic ester via changing the reaction conditions. Finally, the possible reaction mechanism is determined through fluorescence quenching and turn on/off experiments.

Graphical abstract: Visible-light-mediated borylation of aryl and alkyl halides with a palladium complex

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Article information


Submitted
06 Jan 2020
Accepted
13 May 2020
First published
14 May 2020

Org. Biomol. Chem., 2020, Advance Article
Article type
Communication

Visible-light-mediated borylation of aryl and alkyl halides with a palladium complex

J. Zhao, Z. Zhou, Y. Zhang, X. Su, X. Chen and Y. Liang, Org. Biomol. Chem., 2020, Advance Article , DOI: 10.1039/D0OB00028K

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