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Chemical transformations of quaternary ammonium salts via C-N bond cleavage

Abstract

Quaternary ammonium salts are readily prepared and show good reactivity in various organic transformations via C−N bond cleavage. In this review we summerize reactions of aryl, benzyl, allylic and propargyl quaternary ammonium salts including cross-coupling with organometallic reagents, as arylation or benzylation reagents in C-H functionalization, reductive deamination, reductive coupling, nucleophilic substitution, carboxylation with CO2, and carbonylation with CO to construct C-C, C-H and C-heteroatom bonds.

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Article information


Submitted
16 Dec 2019
Accepted
14 Jan 2020
First published
14 Jan 2020

Org. Biomol. Chem., 2020, Accepted Manuscript
Article type
Review Article

Chemical transformations of quaternary ammonium salts via C-N bond cleavage

Z. Wang and B. Yang, Org. Biomol. Chem., 2020, Accepted Manuscript , DOI: 10.1039/C9OB02667C

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