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Nickel nanocrystal/nitrogen-doped carbon composites as efficient and carbon monoxide-resistant electrocatalysts for methanol oxidation reactions

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Abstract

High-performance electrocatalysts for the methanol oxidation reaction (MOR) are the key to advance the application of direct methanol fuel cells. Pt-Based electrocatalysts for the MOR are limited due to their high cost, low stability and poor resistance to carbon monoxide (CO) poisoning. The development of non-noble metal-based electrocatalysts for the MOR with high activity and good stability is desired, but it remains a challenge. Herein, we report a simple strategy to prepare nickel nanocrystals embedded in a nitrogen-doped carbon matrix (Ni/N–C composite) by pyrolysis of Ni-coordinated polyaniline–poly(vinyl alcohol) hydrogels. These in situ generated Ni nanocrystals serve as active electrocatalysts for the MOR, while the nitrogen-doped carbon matrix serves as a conductive support to facilitate electron transfer and also to protect the active Ni nanocrystals. The optimal Ni/N–C@500 electrocatalyst shows a high MOR activity of 147 mA cm−2 at 1.66 V vs. the RHE in alkaline methanol solution, which is outstanding among Ni-based MOR electrocatalysts. Ni/N–C@500 also shows better stability than the Pt/C catalyst in the long-term MOR test at high current densities. Upon CO poisoning, Ni/N–C@500 retains 85% of its MOR activity, far exceeding the performance of the Pt/C catalyst (61% retention). Owing to its facile synthesis, outstanding activity and high stability, the Ni/N–C@500 composite is promising as a low-cost, efficient and CO-resistant electrocatalyst for the MOR.

Graphical abstract: Nickel nanocrystal/nitrogen-doped carbon composites as efficient and carbon monoxide-resistant electrocatalysts for methanol oxidation reactions

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Supplementary files

Article information


Submitted
26 Jun 2020
Accepted
30 Sep 2020
First published
30 Sep 2020

Nanoscale, 2020, Advance Article
Article type
Paper

Nickel nanocrystal/nitrogen-doped carbon composites as efficient and carbon monoxide-resistant electrocatalysts for methanol oxidation reactions

N. Wu, M. Zhai, F. Chen, X. Zhang, R. Guo, T. Hu and M. Ma, Nanoscale, 2020, Advance Article , DOI: 10.1039/D0NR04822D

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