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Issue 26, 2020
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Tunable electrochromic behavior of titanium-based MXenes

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Abstract

Two-dimensional transition metal carbides, nitrides and carbonitrides, popular by the name MXenes, are a promising class of materials as they exhibit intriguing optical, optoelectronic and electrochemical properties. Taking advantage of their metallic conductivity and hydrophilicity, titanium carbide MXenes (Ti3C2Tx and others) are used to fabricate solution processable transparent conducting electrodes (TCEs) for the design of three-electrode electrochromic cells. However, the tunable electrochromic behavior of various titanium-based MXene compositions across the entire visible spectrum has not yet been demonstrated. Here, we investigate the intrinsic electrochromic properties of titanium-based MXenes, Ti3C2Tx, Ti3CNTx, Ti2CTx, and Ti1.6Nb0.4CTx, where individual MXenes serve as a transparent conducting, electrochromic, and plasmonic material layer. Plasmonic extinction bands for Ti3C2Tx, Ti2CTx and Ti1.6Nb0.4CTx are centered at 800, 550 and 480 nm, which are electrochemically tunable to 630, 470 and 410 nm, respectively, whereas Ti3CNTx shows a reversible change in transmittance in the wide visible range. Additionally, the switching rates of MXene electrodes with no additional transparent conductor electrodes are estimated and correlated with the respective electrical figure of merit values. This study demonstrates that MXene-based electrochromic cells are tunable in the entire visible spectrum and suggests the potential of the MXene family of materials in optoelectronic, plasmonic, and photonic applications, such as tunable visible optical filters and modulators, to name a few.

Graphical abstract: Tunable electrochromic behavior of titanium-based MXenes

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Supplementary files

Article information


Submitted
04 Apr 2020
Accepted
10 Jun 2020
First published
10 Jun 2020

Nanoscale, 2020,12, 14204-14212
Article type
Paper

Tunable electrochromic behavior of titanium-based MXenes

G. Valurouthu, K. Maleski, N. Kurra, M. Han, K. Hantanasirisakul, A. Sarycheva and Y. Gogotsi, Nanoscale, 2020, 12, 14204
DOI: 10.1039/D0NR02673E

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