Jump to main content
Jump to site search


Ultra-thin carbon nanofibers based on graphitization of near-field electrospun polyacrylonitrile

Abstract

A novel manufacturing means for arrays of carbon fibers with diameters of less than 10 nm has been developed. The method improves dramatically upon the state of the art of making carbon fibers by pyrolysis of near field electrospun (NFES) polyacrylonitrile (PAN) fibers. The conductive nature of the PAN ink, a touch and retract mode of the droplet at the ejector needle tip and a rotating drum for jet initiation as well as a tight control of the ink flow and droplet shape with a porous paper enable continuous near field electrospinning at an ultra-low voltage of 35V - far below current low-voltage NFES practice. By pyrolyzing the thus obtained thinner PAN nanofibers on carbon scaffolds a dramatic further shrinkage of the diameter leads to ultrathin carbon nanofibers e.g. from a ~245nm polymer fiber to a ~5nm carbon fiber i.e. a 4900 % reduction in fiber diameter. To increase and survive the thinning during the pyrolysis process, PAN stabilization at a relatively low temperature (115 °C) and carbon support scaffolds are implemented to provide just the right amount of tension of the suspended polymer nanofibers. A small inter-fiber spacing (< 8 µm) of the ultrathin carbon fibers in an array is achieved by simultaneously controlling the linear speed of the spinneret and the rotational speed of the collector. In one application, we demonstrate aligned ultra-thin carbon fibers freely suspended and in good ohmic contact with carbon scaffolds on a silicon substrate.

Back to tab navigation

Article information


Submitted
02 Jan 2020
Accepted
09 Mar 2020
First published
10 Mar 2020

Nanoscale, 2020, Accepted Manuscript
Article type
Paper

Ultra-thin carbon nanofibers based on graphitization of near-field electrospun polyacrylonitrile

J. Deng, C. Liu and M. J. Madou, Nanoscale, 2020, Accepted Manuscript , DOI: 10.1039/D0NR00031K

Social activity

Search articles by author

Spotlight

Advertisements