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Issue 14, 2020
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An anisotropic layer-by-layer carbon nanotube/boron nitride/rubber composite and its application in electromagnetic shielding

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Abstract

Multifunctional polymer composites with anisotropic properties are attracting interest as they fulfil the growing demand of multitasking materials. In this work, anisotropic polymer composites have been fabricated by combining the layer-by-layer (LBL) filtration method with the alternative assembling of carbon nanotubes (CNTs) and hexagonal boron nitride flakes (hBN) on natural rubber latex particles (NR). The layered composites exhibit anisotropic thermal and electrical conductivities, which are tailored through the layer formulations. The best composite consists of four layers of NR modified with 8 phr (parts per Hundred Rubber) CNTs (∼7.4 wt%) and four alternate layers with 12 phr hBN (∼10.7 wt%). The composites exhibit an electromagnetic interference (EMI) shielding effectiveness of 22.41 ± 0.14 dB mm−1 at 10.3 GHz and a thermal conductivity equal to 0.25 W m−1 K−1. Furthermore, when the layered composite is used as an electrical thermal heater the surface reaches a stable temperature of ∼103 °C in approx. 2 min, with an input bias of 2.5 V.

Graphical abstract: An anisotropic layer-by-layer carbon nanotube/boron nitride/rubber composite and its application in electromagnetic shielding

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Supplementary files

Article information


Submitted
18 Dec 2019
Accepted
15 Mar 2020
First published
16 Mar 2020

Nanoscale, 2020,12, 7782-7791
Article type
Paper

An anisotropic layer-by-layer carbon nanotube/boron nitride/rubber composite and its application in electromagnetic shielding

Y. Zhan, E. Lago, C. Santillo, A. E. Del Río Castillo, S. Hao, G. G. Buonocore, Z. Chen, H. Xia, M. Lavorgna and F. Bonaccorso, Nanoscale, 2020, 12, 7782
DOI: 10.1039/C9NR10672C

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