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Issue 2, 2020
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Optical properties of symmetry-breaking tetrahedral nanoparticles

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Spectrally rich but geometrically simple plasmonic metallic nanoparticles are highly favored in nanophotonics. However, they remain elusive owing to the symmetry-induced mode degeneracy and interband transition-induced plasmonic damping. Hence, most nanoparticles exhibit a single major extinction peak originating from the lowest-order dipole resonance. In this study, we uncover that even a simple tetrahedral nanoparticle supports rich spectral features due to symmetry breaking. This discovery runs counter to the reported gold tetrahedral nanoparticles, where only a single extinction peak was observed. We find that, in the case of a tetrahedral nanoparticle, the plasmonic quadrupole vertex mode becomes a bright mode and hybridizes with the dipole vertex mode, which splits the extinction peak and contributes to spectral diversity and tunability. The peak splitting is also found to be sensitively dependent on the roundness of vertices and edges. Furthermore, the tetrahedral depolarization factors are determined using the previously generalized absorption coefficient. We envision that this work will not only help fill the gap in understanding the optical properties enriched by symmetry breaking but also guide the superior probe design by combining spectral tunability with geometric simplicity of the nanoparticle.

Graphical abstract: Optical properties of symmetry-breaking tetrahedral nanoparticles

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Article information

04 Oct 2019
03 Dec 2019
First published
03 Dec 2019

Nanoscale, 2020,12, 832-842
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Optical properties of symmetry-breaking tetrahedral nanoparticles

P. Zheng, D. Paria, H. Wang, M. Li and I. Barman, Nanoscale, 2020, 12, 832
DOI: 10.1039/C9NR08515G

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