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An invocation for computational evaluation of isomerization transforms: cationic skeletal reorganizations as a case study

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Abstract

Covering: 2010 to 2020

This review article describes how cationic rearrangement reactions have been used in natural product total synthesis over the last decade as a case study for the many productive ways by which isomerization reactions are enabling for synthesis. This review argues that isomerization reactions in particular are well suited for computational evaluation, as relatively simple calculations can provide significant insight.

Graphical abstract: An invocation for computational evaluation of isomerization transforms: cationic skeletal reorganizations as a case study

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Article information


Submitted
05 Feb 2020
First published
15 Sep 2020

Nat. Prod. Rep., 2020, Advance Article
Article type
Review Article

An invocation for computational evaluation of isomerization transforms: cationic skeletal reorganizations as a case study

A. W. Schuppe, Y. Liu and T. R. Newhouse, Nat. Prod. Rep., 2020, Advance Article , DOI: 10.1039/D0NP00005A

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